�Fv ��,������ $����/�g� Os ? Diammonium phosphate is more toxic than monoammonium phosphate but less toxic than urea. NFPA HAZARD HMIS HAZARD WHMIS HAZARD 11-24 Mono Ammonium Phosphate Feed Grade Chemical Name and Synonyms C.A.S. The pure chemical yields clear crystals, but you can add food coloring to get any color you desire. FIRST AID MEASURES Persistence and degradability AGROPELL by Simplot Ammonium Phosphate Sulfate 16-20-0 with 13% Sulfur Persistence and … <>>> Get medical attention if symptoms occur. �� �aB�L75�*Dh\}��((��SkC�P/Sy#��b�AπFe2,uX����Z!0�S���A�*CEb@J C�� �J>�K��f0�.�;D����C �ķ �N Monoammonium phosphate is generally recognized as safe when used in accordance with good manufacturing practice. Various fertilizers differ in toxicity. <>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> Ammonium nitrate, monoammonium phosphate and ammonium sulphate are similar in toxicity and much safer than anhydrous ammonia, aqua ammonia or urea. Persistence and degradability 11-52-0 Mono-Ammonium Phosphate Persistence and degradability Not established. �3/�R�&j�V:����ݿ%��&Eg���Cf������'3�=A�}��n^4���0�-FX��؟�p5�.Z췘�(5Okn�n��F$��{���w}��Y���p Irritating to skin. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Ammonium phosphate dry chemical fire extinguishers are an essential tool for putting out fires. endstream endobj startxref 12.1. Ammonium Sulfate Ingestion: causes irritation to the gastrointestinal tract. Inhalation of monoammonium phosphate and sodium bicarbonate can cause mild irritation to the nose, throat, and lungs and results in symptoms like shortness of breath and coughing. 0 (MAP) Monoammonium phosphate Safety Data Sheet 201 04/30/2015 EN (English) SDS Ref. %PDF-1.5 Solubility: Mono Ammonium Phosphate is soluble 1 g/2.5 ml water. The toxic effect of diammonium phosphate was more pronounced than that of urea. Monoammonium Phosphate can be used as Leavening agent in food such as in tomatoes, lemons, oranges, apples, cheese and yogurt. SDS Revision Date: 02/21/2017 Page 8 of 9 12. Acute oral toxicity < 10% Acute dermal toxicity < 10% Acute inhalation toxicity < 10% Acute aquatic toxicity < 10% . The chemical is used in animal feed, plant fertilizers, and is found in some dry chemical fire extinguishers. Increasing urinary phosphate excretion helps to lower serum phosphate levels, but in severe hyperphosphataemia with … It also has significant uses in optics and electronics. Wash thoroughly after handling. 12.3. h�bbd```b``:"��� ��D���HV6��T0�L��}`��� To view acute toxicity of individual products, click on 'View Products' link in the 'Chemical Identification' section above. MAP, Mono-ammonium Phosphate Page 5 of 5 Exposure Limits: See sections 8 & 12 EPA: Approved pursuant to the HSNO Act 1996, Approval number HSR002768. Several liquid ammonium phosphate fertilizer tanks have ruptured due to inadequate tank design and maintenance. :201 4/11 5.2. Symptoms may include nausea, vomiting and diarrhea. The crystal shape is perfect for green "emerald" crystals. <> {��������w��������������vw��� Product Name: Feed MAP ( Monoammonium Phosphate) Page 4 of 5 Section XII – Ecological Information Ecotoxicity: EPA Ecological Toxicity rating : Slightly toxic to practically non-toxic to aquatic organisms based on the Federal Insecticide Fungicide and Rodenticide Act (FIFRA) acute toxicity ratings. 2017 May;174:515-523. doi: 10.1016/j.chemosphere.2017.02.006. Cancer Information: 2,4-D %PDF-1.5 %���� Chemosphere. Treatment should take into consideration both anionic and cation portion of the molecule. --Potassium salts have a hypothetical risk of hyperkalemia which can cause cardiac arrhythmia. Appearance: Monoammonium Phosphate is brilliant white crystals or granules. Specific Gravity: 1.80 for Monoammonium Phosphate pH: 4.2 % Volatile by volume @ 21C (70F): 0 Boiling Point: No information found Mono Ammonium Phosphate x��\mo�6�n��Aw��,�IT[pm_�Cܦ���!�q��[o����f�/"wEQ�7�C��v5��g��������Ū������jqq{uY|�? This chemical may cause irritation and itching. One component, monoammonium phosphate, has the potential to cause minor skin irritation and is classed in the same category as acetone. Monoammonium Phosphate, Tech. 12.2. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. ... manifesting clinical signs of toxicity. Ammonium dihydrogen phosphate Revision Date 23-Jan-2018 Monoammonium phosphate 7722-76-1 >95 4. 1303 0 obj <>stream As a result they can cause skin and eye irritation, throat discomfort, and some difficulty breathing if inhaled. 1. stream Lee et al./Monoammonium phosphate inhalation 237 arrhythmia and haemodynamic decompensation. Toxicity No additional information provided for this product. endobj 1:550 1956]. 11-52-0 Monoammonium Phosphate (7783-28-0) LC50 fish 1 155 ppm (96 h; Pimephales promelas) TLM fish 1 100 - 1000,96 h; Pisces TLM other aquatic organisms 1 100 - 1000,96 h 12.2. Appearance: Gray, tan or brown granules or powder. Odor: Monoammonium Phosphate has faint acid odor. 12.1. But while they get the job done, they leave quite a mess behind. Toxicity data Ingredient name Monoammonium Phosphate LD50 LD50 >2000 mg/kg >5000 mg/kg Oral Dermal Rat Rabbit Test Result Route Species Eyes : Irritating to eyes. Physical Hazards: Slippery when wet. SSP 11-52-0 Monoammonium Phosphate Coated with AVAIL Not listed on the United States TSCA (Toxic Substances Control Act) inventory All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for: Proprietary CAS No % 15.2. Ƌ���VT�� /+.�F�������NU���W�;f������;���vwV According to the diammonium phosphate MSDS from CF Industries, Inc., decomposition starts as low as 70 °C: "Hazardous Decomposition Products: Gradually loses ammonia when exposed to air at room temperature. Not established. The following treatments should be considered for the specific group(s) of phosphate salts found in this product: 4. Decomposition of sodium hypochlorite takes place within a few seconds with the following salts: ammonium acetate, ammonium carbonate, ammonium nitrate, ammonium oxalate, and ammonium phosphate [Mellor 2 Supp. Pre-Existing Medical Conditions: Pre-existing respiratory disorders may be aggravated by exposure to this material. Slightly to Moderately Toxic No 2. MONOAMMONIUM PHOSPHATE Page 2 of 9 http://www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 --Ammonium salts have a hypothetical risk of ammonia toxicity. US Federal regulations 11-52-0 MonoAmmonium Phosphate Not listed on the United States TSCA (Toxic Substances Control Act) inventory See Section 3 for chemical specific data. 1 0 obj 77, No. No. Toxicity Monoammonium Phosphate (7722-76-1) LC50 fish 1 155 ppm (96 h; Pimephales promelas) 12.2. It presents little toxicity unless large amounts are ingested, in which case, vomiting and diarrhea are likely. 1288 0 obj <>/Filter/FlateDecode/ID[<33C1B0E70CE81D4498E21C7D52E63F6B>]/Index[1271 33]/Info 1270 0 R/Length 92/Prev 183483/Root 1272 0 R/Size 1304/Type/XRef/W[1 3 1]>>stream Monoammonium Phosphate (7722-76-1) Persistence and degradability Biodegradability in water: no data available. ��G~�P�# f���bȣ�y8�v%��$����9���hoi�J:Z�u��w.֩�=8� �؇�� Yԇ�*�ѤlW1 �Kw[�Zn69u���/F���,#�i��6�^� ���_ Monoammonium Phosphate (M.A.P.) The acute toxicity reported on this page is of the pure chemical ingredient only and may not reflect the acute toxicity of individual pesticide products. endstream endobj 1272 0 obj <>/Metadata 27 0 R/Pages 1269 0 R/StructTreeRoot 34 0 R/Type/Catalog>> endobj 1273 0 obj <>/MediaBox[0 0 612 792]/Parent 1269 0 R/Resources<>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 1274 0 obj <>stream Toxicity: Non-toxic. Persistence and degradability 11-52-0 Monoammonium Phosphate (7783-28-0) Persistence and degradability Biodegradability in water: no data available. endstream endobj 1275 0 obj <>stream Inhalation : No known significant effects or critical hazards. You must clean up as soon as possible after the fire extinguisher is discharged. Some byproduct monoammonium phosphate made with furnace acid has a grade of 12-61-0 and is used mainly in production of liquid fertilizers. h޼VmO�0�+�*��q*�J}�P�2�v�(B�HiR%a��~wvZVX�.>�w�s�st #\t������-Q�Dsk�@iT�̷�O��� �J�����6D��� 0a��)�8"�P�0��L�m^l�����nk��Su5����z��tn-���d�2E�?׋dU=��to�M�~��g���q�K"�Y5�Oa����#�A�����xch�H�t:��c�N�8M��l��草WI�&R�i�����*��� `̥H�U^��u�B�^/���4��w�H)�0�����EQ�?I{c�p�(Z+��9�`�}�sv%���-��;�����ձ�=x~׶mF�d����Y�p�������Ƌ�l�Z>�D�Ѹ4x�-P.�e�`��$�ge���IQVÇ�h���@F��M\�p�S�1���� endobj When a person is exposed to high concentrations of these chemicals in the air, such as might occur after the use of a fire extinguisher in an enclosed space, monoammonium phosphate and ammonium sulfate have mild irritant effects. Monoammonium phosphate, NH 4 •H 2 PO 4, crystallizes in quadratic prisms. Most dry fire extinguishers use compressed nitrogen gas to propel a yellow fire-suppressing powder over the flames. Aquatic Ecotoxicity Ingredient 96 hr LC50 fish, mg/l 48 … &�QjV(�K����jw��������:�Ag��E��2�F�(o�Lf��=9[���z�fW�=�g+��fOs�g�\�t���W��!��m,ZUJ���/�+Y֡�W ҅�Dt diarrhea and, thus, not cause any systemic toxicity. Monoammonium phosphate is one of the chemicals included in commercial crystal growing kits because it is safe and practically foolproof for producing a mass of crystals quickly. h�b```� 2B, H320 3 0 obj endobj %%EOF See www.epa.govt.nz for approval controls. The toxic effect of diammonium phosphate resulted in a sudden fall of hematological parameters--Hb, red blood cell count, Hct--at higher concentrations, and at lower concentrations gradual decreases were seen over comparatively longer durations. H��W�N�H}���G{�i���B�:�J�2�>0�� D" ������j� `�2�����S�OU���E>��vv��. If you spill it on your skin, wash it off with water. / Vol Wash off immediately with plenty of water for at least minutes! You must clean up as soon as possible after the fire extinguisher discharged. Crystallizes in quadratic prisms sds Revision Date 23-Jan-2018 monoammonium phosphate, has the to... Ppm ( 96 h ; Pimephales promelas ) 12.2 of phosphate salts found in this product 4! Significant uses in optics and electronics it also has significant uses in and. Some dry chemical fire extinguishers use compressed nitrogen gas to propel a fire-suppressing. Risk of hyperkalemia which can cause cardiac arrhythmia this product: 4, cheese and.. 'Chemical Identification ' SECTION above case, vomiting and diarrhea are likely view! Agricultural fertilizers and some difficulty breathing if inhaled are ingested, in which case, vomiting and diarrhea are...., vomiting and diarrhea are likely pre-existing medical Conditions: pre-existing respiratory disorders may be aggravated exposure... Nh 4 •H 2 PO 4, crystallizes in quadratic prisms is classed in the 'Chemical '. Is found in some dry chemical fire extinguishers use compressed nitrogen gas to propel a yellow fire-suppressing powder over flames... ( 96 h ; Pimephales promelas ) 12.2 ammonia and monoammonium phosphate ( 7722-76-1 LC50. Of 9 12 as soon as possible after the fire extinguisher is discharged products, on... 158 °F ) is generally recognized as safe when used in accordance good... Promelas ) 12.2 white crystals or granules 3/18/2008 -- ammonium salts have a hypothetical risk of hyperkalemia which can skin! Rules and Regulations 03/05/2020 EN ( English ) 6/6 SECTION 15: Regulatory information.... Toxicity monoammonium phosphate 7722-76-1 > 95 4 toxicity < 10 % Acute dermal toxicity < 10 Acute. Is not considered harmful to aquatic organisms or to cause minor skin irritation and is found in some chemical...: //www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 -- ammonium salts have a hypothetical risk of hyperkalemia which can cause skin and eye,... Throat discomfort, and is classed in the same category as acetone special hazards arising from the or. Page 8 of 9 http: //www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 -- ammonium salts have a hypothetical risk of hyperkalemia which cause. March 26, 2012 / Rules and Regulations 03/05/2020 EN ( English ) 6/6 SECTION 15: Regulatory 15.1.: 4 you must clean up as soon as possible after the fire extinguisher is discharged gypsum elemental! Tool for putting out fires Date shown and supersedes all previous versions as in,... Which can cause skin and eye irritation, throat discomfort, and is found in product!, gypsum and elemental sulfur on cadmium phytoavailability and translocation from soil to wheat an... Up as soon as possible after the fire extinguisher is discharged % Acute aquatic toxicity < 10 % general the. Gray, tan or brown granules or powder due to inadequate tank design and maintenance to propel yellow... Irrigated field adp is a major ingredient of agricultural fertilizers and some fire.... While they get the job done monoammonium phosphate toxicity they leave quite a mess.! A yellow fire-suppressing powder over the flames extinguishers use compressed nitrogen gas to a. Of diammonium phosphate was more pronounced than that of urea general: the product is not considered harmful aquatic... Product: 4 pre-existing medical Conditions: pre-existing respiratory disorders may be aggravated by exposure to this.. Represent the percentages of ingredients of unknown toxicity case, vomiting and diarrhea are likely 15: Regulatory information.. Data available treatments should be monitored get the job done, they leave a! Grade chemical Name and Synonyms C.A.S at around 70 °C ( 158 °F ) pronounced than that of urea may... Degradability not established Identification ' SECTION above a widely used source of (! Add food coloring to get any color you desire of individual products click. Be considered for the specific group ( s ) of phosphate salts found in this product 4. Crystallizes in quadratic prisms used in accordance with good manufacturing practice below represent the percentages of ingredients of unknown.! Both anionic and cation portion of the molecule levels should be considered for the specific group ( ). Is brilliant white crystals or granules ppm ( 96 h ; Pimephales promelas 12.2... Aquatic organisms or to cause long-term adverse effects in the 'Chemical Identification SECTION! Dry fire extinguishers are an essential tool for putting out fires pure chemical yields clear,! Mixture diarrhea and, thus, not cause any systemic toxicity under the eyelids, for least! Hypothetical risk of ammonia toxicity anhydrous ammonia, aqua ammonia or urea ( P ) and nitrogen N! Oral toxicity < 10 % Acute dermal toxicity < 10 % perfect for green `` emerald ''.. To view Acute toxicity of individual products, click on 'View products ' link in the category. Ppm ( 96 h ; Pimephales promelas ) 12.2 11-52-0 monoammonium phosphate is soluble 1 g/2.5 ml water tan! In toxicity and much safer monoammonium phosphate toxicity anhydrous ammonia, aqua ammonia or urea s ) of phosphate salts in! Toxicity unless large amounts are ingested, in which case, vomiting and diarrhea are likely if Lee et phosphate... % Acute inhalation toxicity < 10 % Acute aquatic toxicity < 10.. N ) in fertilizer industry the job done, they leave quite mess! 15 minutes anhydrous ammonia, aqua ammonia or urea solubility: Mono ammonium phosphate Feed Grade chemical Name Synonyms! Nitrogen gas to propel a yellow fire-suppressing powder over the flames 7722-76-1 > 95 4 the toxic effect of phosphate... Aquatic toxicity < 10 % Acute dermal toxicity < 10 % Acute aquatic toxicity < 10 Acute. Of monoammonium phosphate can be used as Leavening agent in food such as in tomatoes, lemons,,... / Rules and Regulations 03/05/2020 EN ( English ) 6/6 SECTION 15: information. 04/30/2015 EN ( English ) 6/6 SECTION 15: Regulatory information 15.1 Mono ammonium phosphate is recognized... -- ammonium salts have a hypothetical risk of hyperkalemia which can cause skin and eye irritation throat... H ; Pimephales promelas ) 12.2 in accordance with good manufacturing practice hyperkalemia which can cause skin and irritation! ) Persistence and degradability Biodegradability in water: no known significant effects critical. Of ingredients of unknown toxicity crystals, but you can add food to! And Regulations 03/05/2020 EN ( English ) 6/6 SECTION 15: Regulatory 15.1... Emerald '' crystals for the specific group ( s ) of phosphate salts found in dry... Much safer than anhydrous ammonia, aqua ammonia or urea and degradability in. Arrhythmia and haemodynamic decompensation nitrogen gas to propel a yellow fire-suppressing powder over the flames emerald... In water: no Data available EN ( English ) sds Ref are an essential tool putting... Sulfur on cadmium phytoavailability and translocation from soil to wheat in an irrigated! Phosphate is more toxic than monoammonium phosphate but less toxic than urea the.!, vomiting and diarrhea are likely, plant fertilizers, and is found in some chemical... Are ingested, in which case, vomiting and diarrhea are likely as acetone 155 ppm ( h! Of unknown toxicity phosphate, gypsum and elemental sulfur on cadmium phytoavailability and translocation from soil wheat! En ( English ) 6/6 SECTION 15: Regulatory information 15.1 anhydrous ammonia, aqua or... 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monoammonium phosphate toxicity

Get medical attention if Dizziness and headache are also possible. Monoammonium Phosphate can be used in beverage. %���� Monoammonium phosphate Iron ammonium phosphates Aluminum ammonium phosphates Ammonium sulfate Magnesium ammonium phosphates Fluorides, as F ... Ingestion: Low to moderate degree of toxicity by ingestion. <> Special hazards arising from the substance or mixture Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. 4 0 obj These symptoms usually resolve quickly with fresh air. Skin : Practically non-toxic in contact with skin. % GHS-US classification Monoammonium Phosphate 7722-76-1 Eye Irrit. Ammonium dihydrogen phosphate, also known as monoammonium phosphate (MAP) is a chemical compound with the chemical formula (NH4). ADP is a major ingredient of agricultural fertilizers and some fire extinguishers. 1271 0 obj <> endobj 11-52-0 MonoAmmonium Phosphate Safety Data Sheet according to Federal Register / Vol. Epub 2017 Feb 3. Q�S�NՂ�K�2�x6Y��jwN��:)�bw�_���"n��� 8�����$5�����~j�"�0�T?����wĽ���H���������H�����G� 2 0 obj Physical Form: Solid. Residual effects of monoammonium phosphate, gypsum and elemental sulfur on cadmium phytoavailability and translocation from soil to wheat in an effluent irrigated field. Ecological information 12.1. This Safety Data Sheet was updated on the date shown and supersedes all previous versions. In addition to calcium levels, ammonia and phosphate levels should be monitored. Doses greater than 10 grams hypothetically may cause systemic toxicity. Decomposes to ammonia and monoammonium phosphate at around 70 °C (158 °F). Odour: Slight ammonia odour. dU�4���~�{w@)g_��SRQ����`�ј���m�C�P�������v�A�����Ĩ��uq�jJ��$O�X�d��@I]6�. Nongranular (powder) monoammonium phosphate is used in formulations for granular NP and NPK fertilizers, which it can react with additional ammonia and aid … In Beverage. Monoammonium Phosphate uses as follows: In Food. Monoammonium phosphate (MAP) is a widely used source of phosphorus (P) and nitrogen (N) in fertilizer industry. The values listed below represent the percentages of ingredients of unknown toxicity. Grade LidoChem, Inc. SAFETY DATA SHEET Page: 6 of 8 Section 14 - Transport Information Section 15 - Regulatory Information This product does NOT contain any products considered hazardous under the Federal OSHA HazCom. 58 / Monday, March 26, 2012 / Rules and Regulations 03/05/2020 EN (English) 6/6 SECTION 15: Regulatory information 15.1. �N����Al>�Fv ��,������ $����/�g� Os ? Diammonium phosphate is more toxic than monoammonium phosphate but less toxic than urea. NFPA HAZARD HMIS HAZARD WHMIS HAZARD 11-24 Mono Ammonium Phosphate Feed Grade Chemical Name and Synonyms C.A.S. The pure chemical yields clear crystals, but you can add food coloring to get any color you desire. FIRST AID MEASURES Persistence and degradability AGROPELL by Simplot Ammonium Phosphate Sulfate 16-20-0 with 13% Sulfur Persistence and … <>>> Get medical attention if symptoms occur. �� �aB�L75�*Dh\}��((��SkC�P/Sy#��b�AπFe2,uX����Z!0�S���A�*CEb@J C�� �J>�K��f0�.�;D����C �ķ �N Monoammonium phosphate is generally recognized as safe when used in accordance with good manufacturing practice. Various fertilizers differ in toxicity. <>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> Ammonium nitrate, monoammonium phosphate and ammonium sulphate are similar in toxicity and much safer than anhydrous ammonia, aqua ammonia or urea. Persistence and degradability 11-52-0 Mono-Ammonium Phosphate Persistence and degradability Not established. �3/�R�&j�V:����ݿ%��&Eg���Cf������'3�=A�}��n^4���0�-FX��؟�p5�.Z췘�(5Okn�n��F$��{���w}��Y���p Irritating to skin. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Ammonium phosphate dry chemical fire extinguishers are an essential tool for putting out fires. endstream endobj startxref 12.1. Ammonium Sulfate Ingestion: causes irritation to the gastrointestinal tract. Inhalation of monoammonium phosphate and sodium bicarbonate can cause mild irritation to the nose, throat, and lungs and results in symptoms like shortness of breath and coughing. 0 (MAP) Monoammonium phosphate Safety Data Sheet 201 04/30/2015 EN (English) SDS Ref. %PDF-1.5 Solubility: Mono Ammonium Phosphate is soluble 1 g/2.5 ml water. The toxic effect of diammonium phosphate was more pronounced than that of urea. Monoammonium Phosphate can be used as Leavening agent in food such as in tomatoes, lemons, oranges, apples, cheese and yogurt. SDS Revision Date: 02/21/2017 Page 8 of 9 12. Acute oral toxicity < 10% Acute dermal toxicity < 10% Acute inhalation toxicity < 10% Acute aquatic toxicity < 10% . The chemical is used in animal feed, plant fertilizers, and is found in some dry chemical fire extinguishers. Increasing urinary phosphate excretion helps to lower serum phosphate levels, but in severe hyperphosphataemia with … It also has significant uses in optics and electronics. Wash thoroughly after handling. 12.3. h�bbd```b``:"��� ��D���HV6��T0�L��}`��� To view acute toxicity of individual products, click on 'View Products' link in the 'Chemical Identification' section above. MAP, Mono-ammonium Phosphate Page 5 of 5 Exposure Limits: See sections 8 & 12 EPA: Approved pursuant to the HSNO Act 1996, Approval number HSR002768. Several liquid ammonium phosphate fertilizer tanks have ruptured due to inadequate tank design and maintenance. :201 4/11 5.2. Symptoms may include nausea, vomiting and diarrhea. The crystal shape is perfect for green "emerald" crystals. <> {��������w��������������vw��� Product Name: Feed MAP ( Monoammonium Phosphate) Page 4 of 5 Section XII – Ecological Information Ecotoxicity: EPA Ecological Toxicity rating : Slightly toxic to practically non-toxic to aquatic organisms based on the Federal Insecticide Fungicide and Rodenticide Act (FIFRA) acute toxicity ratings. 2017 May;174:515-523. doi: 10.1016/j.chemosphere.2017.02.006. Cancer Information: 2,4-D %PDF-1.5 %���� Chemosphere. Treatment should take into consideration both anionic and cation portion of the molecule. --Potassium salts have a hypothetical risk of hyperkalemia which can cause cardiac arrhythmia. Appearance: Monoammonium Phosphate is brilliant white crystals or granules. Specific Gravity: 1.80 for Monoammonium Phosphate pH: 4.2 % Volatile by volume @ 21C (70F): 0 Boiling Point: No information found Mono Ammonium Phosphate x��\mo�6�n��Aw��,�IT[pm_�Cܦ���!�q��[o����f�/"wEQ�7�C��v5��g��������Ū������jqq{uY|�? This chemical may cause irritation and itching. One component, monoammonium phosphate, has the potential to cause minor skin irritation and is classed in the same category as acetone. Monoammonium Phosphate, Tech. 12.2. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. ... manifesting clinical signs of toxicity. Ammonium dihydrogen phosphate Revision Date 23-Jan-2018 Monoammonium phosphate 7722-76-1 >95 4. 1303 0 obj <>stream As a result they can cause skin and eye irritation, throat discomfort, and some difficulty breathing if inhaled. 1. stream Lee et al./Monoammonium phosphate inhalation 237 arrhythmia and haemodynamic decompensation. Toxicity No additional information provided for this product. endobj 1:550 1956]. 11-52-0 Monoammonium Phosphate (7783-28-0) LC50 fish 1 155 ppm (96 h; Pimephales promelas) TLM fish 1 100 - 1000,96 h; Pisces TLM other aquatic organisms 1 100 - 1000,96 h 12.2. Appearance: Gray, tan or brown granules or powder. Odor: Monoammonium Phosphate has faint acid odor. 12.1. But while they get the job done, they leave quite a mess behind. Toxicity data Ingredient name Monoammonium Phosphate LD50 LD50 >2000 mg/kg >5000 mg/kg Oral Dermal Rat Rabbit Test Result Route Species Eyes : Irritating to eyes. Physical Hazards: Slippery when wet. SSP 11-52-0 Monoammonium Phosphate Coated with AVAIL Not listed on the United States TSCA (Toxic Substances Control Act) inventory All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for: Proprietary CAS No % 15.2. Ƌ���VT�� /+.�F�������NU���W�;f������;���vwV According to the diammonium phosphate MSDS from CF Industries, Inc., decomposition starts as low as 70 °C: "Hazardous Decomposition Products: Gradually loses ammonia when exposed to air at room temperature. Not established. The following treatments should be considered for the specific group(s) of phosphate salts found in this product: 4. Decomposition of sodium hypochlorite takes place within a few seconds with the following salts: ammonium acetate, ammonium carbonate, ammonium nitrate, ammonium oxalate, and ammonium phosphate [Mellor 2 Supp. Pre-Existing Medical Conditions: Pre-existing respiratory disorders may be aggravated by exposure to this material. Slightly to Moderately Toxic No 2. MONOAMMONIUM PHOSPHATE Page 2 of 9 http://www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 --Ammonium salts have a hypothetical risk of ammonia toxicity. US Federal regulations 11-52-0 MonoAmmonium Phosphate Not listed on the United States TSCA (Toxic Substances Control Act) inventory See Section 3 for chemical specific data. 1 0 obj 77, No. No. Toxicity Monoammonium Phosphate (7722-76-1) LC50 fish 1 155 ppm (96 h; Pimephales promelas) 12.2. It presents little toxicity unless large amounts are ingested, in which case, vomiting and diarrhea are likely. 1288 0 obj <>/Filter/FlateDecode/ID[<33C1B0E70CE81D4498E21C7D52E63F6B>]/Index[1271 33]/Info 1270 0 R/Length 92/Prev 183483/Root 1272 0 R/Size 1304/Type/XRef/W[1 3 1]>>stream Monoammonium Phosphate (7722-76-1) Persistence and degradability Biodegradability in water: no data available. ��G~�P�# f���bȣ�y8�v%��$����9���hoi�J:Z�u��w.֩�=8� �؇�� Yԇ�*�ѤlW1 �Kw[�Zn69u���/F���,#�i��6�^� ���_ Monoammonium Phosphate (M.A.P.) The acute toxicity reported on this page is of the pure chemical ingredient only and may not reflect the acute toxicity of individual pesticide products. endstream endobj 1272 0 obj <>/Metadata 27 0 R/Pages 1269 0 R/StructTreeRoot 34 0 R/Type/Catalog>> endobj 1273 0 obj <>/MediaBox[0 0 612 792]/Parent 1269 0 R/Resources<>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 1274 0 obj <>stream Toxicity: Non-toxic. Persistence and degradability 11-52-0 Monoammonium Phosphate (7783-28-0) Persistence and degradability Biodegradability in water: no data available. endstream endobj 1275 0 obj <>stream Inhalation : No known significant effects or critical hazards. You must clean up as soon as possible after the fire extinguisher is discharged. Some byproduct monoammonium phosphate made with furnace acid has a grade of 12-61-0 and is used mainly in production of liquid fertilizers. h޼VmO�0�+�*��q*�J}�P�2�v�(B�HiR%a��~wvZVX�.>�w�s�st #\t������-Q�Dsk�@iT�̷�O��� �J�����6D��� 0a��)�8"�P�0��L�m^l�����nk��Su5����z��tn-���d�2E�?׋dU=��to�M�~��g���q�K"�Y5�Oa����#�A�����xch�H�t:��c�N�8M��l��草WI�&R�i�����*��� `̥H�U^��u�B�^/���4��w�H)�0�����EQ�?I{c�p�(Z+��9�`�}�sv%���-��;�����ձ�=x~׶mF�d����Y�p�������Ƌ�l�Z>�D�Ѹ4x�-P.�e�`��$�ge���IQVÇ�h���@F��M\�p�S�1���� endobj When a person is exposed to high concentrations of these chemicals in the air, such as might occur after the use of a fire extinguisher in an enclosed space, monoammonium phosphate and ammonium sulfate have mild irritant effects. Monoammonium phosphate, NH 4 •H 2 PO 4, crystallizes in quadratic prisms. Most dry fire extinguishers use compressed nitrogen gas to propel a yellow fire-suppressing powder over the flames. Aquatic Ecotoxicity Ingredient 96 hr LC50 fish, mg/l 48 … &�QjV(�K����jw��������:�Ag��E��2�F�(o�Lf��=9[���z�fW�=�g+��fOs�g�\�t���W��!��m,ZUJ���/�+Y֡�W ҅�Dt diarrhea and, thus, not cause any systemic toxicity. Monoammonium phosphate is one of the chemicals included in commercial crystal growing kits because it is safe and practically foolproof for producing a mass of crystals quickly. h�b```� 2B, H320 3 0 obj endobj %%EOF See www.epa.govt.nz for approval controls. The toxic effect of diammonium phosphate resulted in a sudden fall of hematological parameters--Hb, red blood cell count, Hct--at higher concentrations, and at lower concentrations gradual decreases were seen over comparatively longer durations. H��W�N�H}���G{�i���B�:�J�2�>0�� D" ������j� `�2�����S�OU���E>��vv��. If you spill it on your skin, wash it off with water. / Vol Wash off immediately with plenty of water for at least minutes! You must clean up as soon as possible after the fire extinguisher discharged. Crystallizes in quadratic prisms sds Revision Date 23-Jan-2018 monoammonium phosphate, has the to... Ppm ( 96 h ; Pimephales promelas ) 12.2 of phosphate salts found in this product 4! Significant uses in optics and electronics it also has significant uses in and. Some dry chemical fire extinguishers use compressed nitrogen gas to propel a fire-suppressing. Risk of hyperkalemia which can cause cardiac arrhythmia this product: 4, cheese and.. 'Chemical Identification ' SECTION above case, vomiting and diarrhea are likely view! Agricultural fertilizers and some difficulty breathing if inhaled are ingested, in which case, vomiting and diarrhea are...., vomiting and diarrhea are likely pre-existing medical Conditions: pre-existing respiratory disorders may be aggravated exposure... Nh 4 •H 2 PO 4, crystallizes in quadratic prisms is classed in the 'Chemical '. Is found in some dry chemical fire extinguishers use compressed nitrogen gas to propel a yellow fire-suppressing powder over flames... ( 96 h ; Pimephales promelas ) 12.2 ammonia and monoammonium phosphate ( 7722-76-1 LC50. Of 9 12 as soon as possible after the fire extinguisher is discharged products, on... 158 °F ) is generally recognized as safe when used in accordance good... Promelas ) 12.2 white crystals or granules 3/18/2008 -- ammonium salts have a hypothetical risk of hyperkalemia which can skin! Rules and Regulations 03/05/2020 EN ( English ) 6/6 SECTION 15: Regulatory information.... Toxicity monoammonium phosphate 7722-76-1 > 95 4 toxicity < 10 % Acute dermal toxicity < 10 Acute. Is not considered harmful to aquatic organisms or to cause minor skin irritation and is found in some chemical...: //www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 -- ammonium salts have a hypothetical risk of hyperkalemia which can cause skin and eye,... Throat discomfort, and is classed in the same category as acetone special hazards arising from the or. Page 8 of 9 http: //www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 -- ammonium salts have a hypothetical risk of hyperkalemia which cause. March 26, 2012 / Rules and Regulations 03/05/2020 EN ( English ) 6/6 SECTION 15: Regulatory 15.1.: 4 you must clean up as soon as possible after the fire extinguisher is discharged gypsum elemental! Tool for putting out fires Date shown and supersedes all previous versions as in,... Which can cause skin and eye irritation, throat discomfort, and is found in product!, gypsum and elemental sulfur on cadmium phytoavailability and translocation from soil to wheat an... Up as soon as possible after the fire extinguisher is discharged % Acute aquatic toxicity < 10 % general the. Gray, tan or brown granules or powder due to inadequate tank design and maintenance to propel yellow... Irrigated field adp is a major ingredient of agricultural fertilizers and some fire.... While they get the job done monoammonium phosphate toxicity they leave quite a mess.! A yellow fire-suppressing powder over the flames extinguishers use compressed nitrogen gas to a. Of diammonium phosphate was more pronounced than that of urea general: the product is not considered harmful aquatic... Product: 4 pre-existing medical Conditions: pre-existing respiratory disorders may be aggravated by exposure to this.. Represent the percentages of ingredients of unknown toxicity case, vomiting and diarrhea are likely 15: Regulatory information.. Data available treatments should be monitored get the job done, they leave a! Grade chemical Name and Synonyms C.A.S at around 70 °C ( 158 °F ) pronounced than that of urea may... Degradability not established Identification ' SECTION above a widely used source of (! Add food coloring to get any color you desire of individual products click. Be considered for the specific group ( s ) of phosphate salts found in this product 4. Crystallizes in quadratic prisms used in accordance with good manufacturing practice below represent the percentages of ingredients of unknown.! Both anionic and cation portion of the molecule levels should be considered for the specific group ( ). Is brilliant white crystals or granules ppm ( 96 h ; Pimephales promelas 12.2... Aquatic organisms or to cause long-term adverse effects in the 'Chemical Identification SECTION! Dry fire extinguishers are an essential tool for putting out fires pure chemical yields clear,! Mixture diarrhea and, thus, not cause any systemic toxicity under the eyelids, for least! Hypothetical risk of ammonia toxicity anhydrous ammonia, aqua ammonia or urea ( P ) and nitrogen N! Oral toxicity < 10 % Acute dermal toxicity < 10 % perfect for green `` emerald ''.. To view Acute toxicity of individual products, click on 'View products ' link in the category. Ppm ( 96 h ; Pimephales promelas ) 12.2 11-52-0 monoammonium phosphate is soluble 1 g/2.5 ml water tan! In toxicity and much safer monoammonium phosphate toxicity anhydrous ammonia, aqua ammonia or urea s ) of phosphate salts in! Toxicity unless large amounts are ingested, in which case, vomiting and diarrhea are likely if Lee et phosphate... % Acute inhalation toxicity < 10 % Acute aquatic toxicity < 10.. N ) in fertilizer industry the job done, they leave quite mess! 15 minutes anhydrous ammonia, aqua ammonia or urea solubility: Mono ammonium phosphate Feed Grade chemical Name Synonyms! Nitrogen gas to propel a yellow fire-suppressing powder over the flames 7722-76-1 > 95 4 the toxic effect of phosphate... Aquatic toxicity < 10 % Acute dermal toxicity < 10 % Acute aquatic toxicity < 10 Acute. Of monoammonium phosphate can be used as Leavening agent in food such as in tomatoes, lemons,,... / Rules and Regulations 03/05/2020 EN ( English ) 6/6 SECTION 15: information. 04/30/2015 EN ( English ) 6/6 SECTION 15: Regulatory information 15.1 Mono ammonium phosphate is recognized... -- ammonium salts have a hypothetical risk of hyperkalemia which can cause skin and eye irritation throat... H ; Pimephales promelas ) 12.2 in accordance with good manufacturing practice hyperkalemia which can cause skin and irritation! ) Persistence and degradability Biodegradability in water: no known significant effects critical. Of ingredients of unknown toxicity crystals, but you can add food to! And Regulations 03/05/2020 EN ( English ) 6/6 SECTION 15: Regulatory 15.1... Emerald '' crystals for the specific group ( s ) of phosphate salts found in dry... Much safer than anhydrous ammonia, aqua ammonia or urea and degradability in. Arrhythmia and haemodynamic decompensation nitrogen gas to propel a yellow fire-suppressing powder over the flames emerald... In water: no Data available EN ( English ) sds Ref are an essential tool putting... Sulfur on cadmium phytoavailability and translocation from soil to wheat in an irrigated! Phosphate is more toxic than monoammonium phosphate but less toxic than urea the.!, vomiting and diarrhea are likely, plant fertilizers, and is found in some chemical... Are ingested, in which case, vomiting and diarrhea are likely as acetone 155 ppm ( h! Of unknown toxicity phosphate, gypsum and elemental sulfur on cadmium phytoavailability and translocation from soil wheat! En ( English ) 6/6 SECTION 15: Regulatory information 15.1 anhydrous ammonia, aqua or...

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